Effect of V Content on the Microstructure and Mechanical Properties of High-Pressure Torsion Nanostructured CoCrFeMnNiV<sub>x</sub> High-Entropy Alloys

Author(s)
Elena D. Tabachnikova, Sergej N. Smirnov, Yuriy O. Shapovalov, Igor V. Kolodiy, Anastasia V. Levenets, Mikhail A. Tikhonovsky, Michael J. Zehetbauer, Christian Rentenberger, Erhard Schafler, Yi Huang, Terence G. Langdon
Abstract

The article presents investigations of microstructure and low-temperature mechanical properties of nanostructured alloys CoCrFeMnNiVx (x = 0.15–0.75), processed by high-pressure torsion (HPT) at temperatures of 300 and 77 K. While at x ≥ 0.5 the values of microhardness (Hv) and compression yield stress (σ0.2) in samples after HPT at 77 K are larger than those in samples after HPT at 300 K, for x ≤ 0.2 surprisingly the opposite effect is observed. As in case of the undeformed CoCrFeMnNiVx alloys, the behavior for vanadium concentrations x ≥ 0.5 can be related to the formation of tetragonal σ-phase in addition to face-centered cubic matrix, while the anomalous behavior for x ≤ 0.2 arises from the formation of HPT-induced hexagonal martensitic phase. In the low-temperature ranges, i.e., 20–300 K in case of HPT nanostructured CoCrFeMnNiV0.2, and 150–300 K in case of HPT nanostructured CoCrFeMnNiV0.5, dependences of σ0.2(T) show characteristics of thermally activated dislocation movement. For the first time in high-entropy alloys, anomalous dependences of σ0.2(T) at temperatures 4.2–20 K for CoCrFeMnNiV0.2, and at 80–150 K for CoCrFeMnNiV0.5 are found, which indicate at the occurrence of nonthermal inertial dislocation movement.

Organisation(s)
Dynamics of Condensed Systems, Physics of Nanostructured Materials
External organisation(s)
National Academy of Sciences of Ukraine (NASU), National Science Center Kharkiv Institute of Physics and Technology (KIPT), Bournemouth University, University of Southampton
Journal
Advanced Engineering Materials
Volume
26
No. of pages
12
ISSN
1438-1656
DOI
https://doi.org/10.1002/adem.202400692
Publication date
10-2024
Peer reviewed
Yes
Austrian Fields of Science 2012
103018 Materials physics, 103042 Electron microscopy
Keywords
ASJC Scopus subject areas
General Materials Science, Condensed Matter Physics
Portal url
https://ucrisportal.univie.ac.at/en/publications/6090d8c8-d551-4d05-be77-1b6b5ca9a344