Peeling graphite layer by layer reveals the charge exchange dynamics of ions inside a solid

Author(s)
Anna Niggas, Sascha Creutzburg, Janine Schwestka, Benjamin Wöckinger, Tushar Gupta, Pedro L. Grande, Dominik Eder, Jose P. Marques, Bernhard C. Bayer, Friedrich Aumayr, Robert Bennett, Richard A. Wilhelm
Abstract

Over seventy years ago, Niels Bohr described how the charge state of an atomic ion moving through a solid changes dynamically as a result of electron capture and loss processes, eventually resulting in an equilibrium charge state. Although obvious, this process has so far eluded direct experimental observation. By peeling a solid, such as graphite, layer by layer, and studying the transmission of highly charged ions through single-, bi- and trilayer graphene, we can now observe dynamical changes in ion charge states with monolayer precision. In addition we present a first-principles approach based on the virtual photon model for interparticle energy transfer to corroborate our findings. Our model that uses a Gaussian shaped dynamic polarisability rather than a spatial delta function is a major step in providing a self-consistent description for interparticle de-excitation processes at the limit of small separations.Ion-solid interactions are governed by a range of complex processes the direct experimental observation of which pose their own set of challenges. Here, the authors present a joint experimental and first-principles approach to study and describe the underlying mechanism of electron capture for an ion travelling through layers of graphene with monolayer precision.

Organisation(s)
Physics of Nanostructured Materials
External organisation(s)
Technische Universität Wien, Helmholtz-Zentrum Dresden-Rossendorf, Universidade Federal do Rio Grande do Sul, Universidade de Lisboa, University of Glasgow
Journal
Communications Physics
Volume
4
No. of pages
9
ISSN
2399-3650
DOI
https://doi.org/10.1038/s42005-021-00686-1
Publication date
08-2021
Peer reviewed
Yes
Austrian Fields of Science 2012
103018 Materials physics
Keywords
Portal url
https://ucris.univie.ac.at/portal/en/publications/peeling-graphite-layer-by-layer-reveals-the-charge-exchange-dynamics-of-ions-inside-a-solid(9ea37942-f82d-43a7-85db-c971c41e8cb4).html