Microstructure of calcite deformed by high-pressure torsion

Author(s)
Roman Schuster, Erhard Schafler, Norbert Schell, Martin Kunz, Rainer Abart
Abstract

Calcite aggregates were deformed to high strain using high-pressure torsion and applying confining pressures of 1-6 GPa and temperatures between room temperature and 450 degrees C. The run products were characterized by X-ray diffraction, and key microstructural parameters were extracted employing X-ray line profile analysis. The dominant slip system was determined as r{10 (1) over bar4} with edge dislocation character. The resulting dislocation density and the size of the coherently scattering domains (CSD) exhibit a systematic dependence on the P-T conditions of deformation. While high pressure generally impedes recovery through reducing point defect mobility, the picture is complicated by pressure-induced phase transformations in the CaCO3 system. Transition from the calcite stability field to those of the high-pressure polymorphs CaCO3-II, CaCO3-III and CaCO3-IIIb leads to a change of the microstructural evolution with deformation. At 450 degrees C and pressures within the calcite stability field, dislocation densities and CSD sizes saturate at shear strains exceeding 10 in agreement with earlier studies at lower pressures. In the stability field of CaCO3-II, the dislocation density exhibits a more complex behavior. Furthermore, at a given strain and strain rate, the dislocation density increases and the CSD size decreases with increasing pressure within the stability fields of either calcite or of the high-pressure polymorphs. There is, however, a jump from high dislocation densities and small CSDs in the upper pressure region of the calcite stability field to lower dislocation densities and larger CSDs in the low-pressure region of the CaCO3-II stability field. This jump is more pronounced at higher temperatures and less so at room temperature. The pressure influence on the deformation-induced evolution of dislocation densities implies that pressure variations may change the rheology of carbonate rocks. In particular, a weakening is expected to occur at the transition from the calcite to the CaCO3-II stability field, if aragonite does not form.

Organisation(s)
Department of Lithospheric Research, Physics of Nanostructured Materials
External organisation(s)
Lawrence Berkeley National Laboratory, Helmholtz-Zentrum Geesthacht - Zentrum für Material- und Küstenforschung
Journal
Tectonophysics
Volume
721
Pages
448-461
No. of pages
14
ISSN
0040-1951
DOI
https://doi.org/10.1016/j.tecto.2017.10.015
Publication date
11-2017
Peer reviewed
Yes
Austrian Fields of Science 2012
Materials physics, General geophysics
Keywords
Portal url
https://ucris.univie.ac.at/portal/en/publications/microstructure-of-calcite-deformed-by-highpressure-torsion(2676caa8-fcf0-44c6-9892-69feaa776210).html