Hexatic phase in covalent two-dimensional silver iodide

Author(s)
Thuy An Bui, David Lamprecht, Jacob Madsen, Marcin Kurpas, Peter Kotrusz, Alexander Markevich, Clemens Mangler, Jani Kotakoski, Lado Filipovic, Jannik C Meyer, Timothy J. Pennycook, Viera Skakalova, Kimmo Mustonen
Abstract

According to the Kosterlitz-Thouless-Halperin-Nelson-Young (KTHNY) theory, the transition from a solid to liquid in two dimensions proceeds through an orientationally ordered liquid-like hexatic phase. However, alternative mixed melting scenarios, in which melting proceeds through the hexatic phase with both continuous and discontinuous transitions, have also been observed in some two-dimensional systems. In this study, we imaged silver iodide embedded in multilayer graphene using time- and temperature-resolved in situ atomic-resolution scanning transmission electron microscopy and nanobeam electron diffraction. We observed the hexatic phase and provide evidence supporting a mixed melting scenario.

Organisation(s)
Physics of Nanostructured Materials
External organisation(s)
Technische Universität Wien, University of Silesia in Katowice, Danubia NanoTech Sro, Slovak Academy of Sciences (SAS), Eberhard Karls Universität Tübingen, University of Antwerp
Journal
Science
Volume
390
Pages
1033-1037
ISSN
0036-8075
DOI
https://doi.org/10.1126/science.adv7915
Publication date
12-2025
Peer reviewed
Yes
Austrian Fields of Science 2012
103009 Solid state physics, 103042 Electron microscopy
Portal url
https://ucrisportal.univie.ac.at/en/publications/fa5c62bd-a999-49f7-a1f7-f99b08c15047