Direct imaging of light-element impurities in graphene reveals triple-coordinated oxygen

Author(s)
Christoph Hofer, Viera Skákalová, Tobias Görlich, Mukesh Tripathi, Andreas Mittelberger, Clemens Mangler, Mohammad Reza Ahmadpour Monazam, Toma Susi, Jani Kotakoski, Jannik C. Meyer
Abstract

Along with hydrogen, carbon, nitrogen and oxygen are the arguably most important elements for organic chemistry. Due to their rich variety of possible bonding configurations, they can form a staggering number of compounds. Here, we present a detailed analysis of nitrogen and oxygen bonding configurations in a defective carbon (graphene) lattice. Using aberration-corrected scanning transmission electron microscopy and single-atom electron energy loss spectroscopy, we directly imaged oxygen atoms in graphene oxide, as well as nitrogen atoms implanted into graphene. The collected data allows us to compare nitrogen and oxygen bonding configurations, showing clear differences between the two elements. As expected, nitrogen forms either two or three bonds with neighboring carbon atoms, with three bonds being the preferred configuration. Oxygen, by contrast, tends to bind with only two carbon atoms. Remarkably, however, triple-coordinated oxygen with three carbon neighbors is also observed, a configuration that is exceedingly rare in organic compounds.

Organisation(s)
Physics of Nanostructured Materials
External organisation(s)
Eberhard Karls Universität Tübingen, Universität Wien
Journal
Nature Communications
Volume
10
ISSN
2041-1723
DOI
https://doi.org/10.1038/s41467-019-12537-3
Publication date
10-2019
Peer reviewed
Yes
Austrian Fields of Science 2012
Electron microscopy
ASJC Scopus subject areas
, ,
Portal url
https://ucris.univie.ac.at/portal/en/publications/direct-imaging-of-lightelement-impurities-in-graphene-reveals-triplecoordinated-oxygen(d0cf672a-b5d9-4d16-b7ba-d699b6697917).html