Fabrication of free-standing pure carbon-based composite material with the combination of sp(2)-sp(3) hybridizations

Author(s)
M. Varga, V. Vretenar, M. Kotlar, V. Skakalova, A. Kromka
Abstract

Composite structures have been in a center of interest for many decades. Carbon–carbon composites combine different carbon-based allotropes. Combining different carbon structures each with its unique property results in a new composite material with designed properties. In this contribution we present a technological procedure for preparation of a new flexible material consisting of single-wall carbon nanotubes (SWNTs) and nanocrystalline diamond (NCD). The fabrication process starts from the preparation of a paper made of SWNTs bundles followed by the CVD-growth of NCD in the interior of the SWNT paper. Keeping balance between the two competing processes during the CVD, i.e. growth of diamond particles versus etching SWNTs, is found as a key factor for the formation of a compact SWNT/NCD composite material. From a technological point of view, both processes are influenced mainly by the CVD conditions (temperature, gas composition, etc.) and/or substrate pretreatment. The essential idea of the diamond integration into the SWNT paper is demonstrated and discussed in more details. The morphology and structural aspects of the prepared composite material are further characterized by scanning electron microscopy and Raman spectroscopy.

Organisation(s)
Physics of Nanostructured Materials
External organisation(s)
Danubia NanoTech Sro, Slovak Academy of Sciences (SAS), Czech Academy of Sciences, Slovak University of Technology in Bratislava
Journal
Applied Surface Science
Volume
308
Pages
211-215
No. of pages
5
ISSN
0169-4332
DOI
https://doi.org/10.1016/j.apsusc.2014.04.137
Publication date
07-2014
Peer reviewed
Yes
Austrian Fields of Science 2012
103020 Surface physics, 103018 Materials physics
Keywords
ASJC Scopus subject areas
Condensed Matter Physics, Physics and Astronomy(all), Surfaces, Coatings and Films, Chemistry(all), Surfaces and Interfaces
Portal url
https://ucris.univie.ac.at/portal/en/publications/fabrication-of-freestanding-pure-carbonbased-composite-material-with-the-combination-of-sp2sp3-hybridizations(c39af622-bee4-4d80-a550-9ccdcf82a0e2).html